Halogen bonding for selective electrochemical separation, path to sustainable chemical processing demonstrated

A team has reported the first demonstration of selective electrochemical separation driven by halogen bonding. This was achieved by engineering a polymer that modulates the charge density on a halogen atom when electricity is applied. The polymer then attracts only certain targets -- such as halides, oxyanions, and even organic molecules -- from organic solutions, a feature that has important implications for pharmaceuticals and chemical synthesis processes.